Question Solved1 Answer Pre-Equilibria Conditions in Reaction Mechanisms CO(9) + Cl2(9) - CoCl2(9) The above reaction obeys the mechanism: Cl2 2cl Fast equilibrium Cl + CO COCI Fast equilibrium Slow COCI + Cl2 , COCl2 + c 201 202 Fast Consider each of the following expressions and select "Yes" or "No" to Indicate which represent a correct statement of the rate law that is consistent with the given mechanism. [CoCl2]/dt = k[Cl21 CoCl2]/dt - k[CI][CO] [CoCl2]/dt - k[CI]2 CoCl2)/dt - k[CO]C1232/3 9 [CoCl21/dt = K[CO][C1212 9 -d[Cl2]/dt = K[C1213/2tcoj ipts Tries 0/5 Suppose that: kg/k.1 - 1*10-2 mol L1, kz/k-2 - 1x106L moi", k3 - 1*10**Lmolls, and ke-1x10'lmoi1,-1 What would be the value of the overall rate constant, k, including the correct units If you are having trouble getting the units correctly formatted, have a dose look at the examples ipts Tries 0/5
31DHR3 The Asker · Chemistry
Transcribed Image Text: Pre-Equilibria Conditions in Reaction Mechanisms CO(9) + Cl2(9) - CoCl2(9) The above reaction obeys the mechanism: Cl2 2cl Fast equilibrium Cl + CO COCI Fast equilibrium Slow COCI + Cl2 , COCl2 + c 201 202 Fast Consider each of the following expressions and select "Yes" or "No" to Indicate which represent a correct statement of the rate law that is consistent with the given mechanism. [CoCl2]/dt = k[Cl21 CoCl2]/dt - k[CI][CO] [CoCl2]/dt - k[CI]2 CoCl2)/dt - k[CO]C1232/3 9 [CoCl21/dt = K[CO][C1212 9 -d[Cl2]/dt = K[C1213/2tcoj ipts Tries 0/5 Suppose that: kg/k.1 - 1*10-2 mol L1, kz/k-2 - 1x106L moi", k3 - 1*10**Lmolls, and ke-1x10'lmoi1,-1 What would be the value of the overall rate constant, k, including the correct units If you are having trouble getting the units correctly formatted, have a dose look at the examples ipts Tries 0/5
More Transcribed Image Text: Pre-Equilibria Conditions in Reaction Mechanisms CO(9) + Cl2(9) - CoCl2(9) The above reaction obeys the mechanism: Cl2 2cl Fast equilibrium Cl + CO COCI Fast equilibrium Slow COCI + Cl2 , COCl2 + c 201 202 Fast Consider each of the following expressions and select "Yes" or "No" to Indicate which represent a correct statement of the rate law that is consistent with the given mechanism. [CoCl2]/dt = k[Cl21 CoCl2]/dt - k[CI][CO] [CoCl2]/dt - k[CI]2 CoCl2)/dt - k[CO]C1232/3 9 [CoCl21/dt = K[CO][C1212 9 -d[Cl2]/dt = K[C1213/2tcoj ipts Tries 0/5 Suppose that: kg/k.1 - 1*10-2 mol L1, kz/k-2 - 1x106L moi", k3 - 1*10**Lmolls, and ke-1x10'lmoi1,-1 What would be the value of the overall rate constant, k, including the correct units If you are having trouble getting the units correctly formatted, have a dose look at the examples ipts Tries 0/5
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{:[Cl_(2)(k_(1))/((k_(-1))/())2u" (fad) "],[a+omega(k_(2)-1)/(k_(k-2))coc " Cfant "],[coa+a_(2)rarr^(k_(3))coc_(2)+a" (slow) "],[2Celongrightarrow^(k_(4))Cl_(2)" (gant) "]:}Ace to steady Stat Approwimation, rate ri dependent on the Slowest 8te:.v=K_(3)[cocl][Cl_(2)]" (1) "Acc-to fre- equilibiuin approwimation," from "step 1rarr(k_(1))/(k_(-1))=([u]^(2))/([u_(2)])"-(2) the "(k_(2))/(k_(2))=([omega l]])/([0][U])" - (3) "Now, foron eqt 3,[coci]=(k_(2))/(k_(-2))[co][a]=(k_(2))/(k_(1))[C_(0)]((k_(1))/(k_(1))[u_(2)])^(1//2)quad(:'" fromeq ... See the full answer